After checking the libretro page of np2kai, I noticed that there are some keyboard buttons mapped to retropad in case we choose Joy2Key (Arrows) or Joy2Key (Keypad). unfortunately there is no Left Shift key (there is left ctrl and right shift )
Anyway, regardless of choosing, in the core options, arrows, keypad or atari joypad, there are no options to map any retropadās key (quick menu -> controls -> port 1 controls -> all options are blank) in the usual unified way.