Seems most of the Game Mode defaults on the TV (if what I’m seeing after reset is what you have) involve Colour Tone as standard (which is a fairly “cool” setting), Contrast Enhancer to High, and Peak Brightness off (along with slight variations on main Colour setting). Might be interesting to play around with different variations on those.
Peak Brightness I always figured would be best left on High, and I’ve had mostly mixed results with Contrast Enhancer due to some desaturation and blow out\black crush issue - that said this was from my experimenting with standard games and movies. How emulation shaders on the TV would react by changing these could be a very different thing.